Salinity: Electrical Conductivity and Total Dissolved Solids
D.L. Sparks
Search for more papers by this authorP.A. Helmke
Search for more papers by this authorR.H. Loeppert
Search for more papers by this authorP. N. Soltanpour
Search for more papers by this authorM. A. Tabatabai
Search for more papers by this authorC. T. Johnston
Search for more papers by this authorM. E. Sumner
Search for more papers by this authorSummary
This chapter describes prevalent laboratory methods for determining salinity based on measurements of electrical conductivity (EC) or total dissolved solids after evaporation at 180°C. It discusses various methods for determining the concentrations of individual inorganic solutes in waters and soil extracts in common use in laboratories having modern instrumentation. The extraction ratios are easier to make than that of saturation, but they are less well related to field soil water composition and content. More importantly, salinity and compositional errors from dispersion, hydrolysis, cation exchange, and mineral dissolution increase as the water/soil ratio increases. Soil salinity may be estimated from measurement of the EC of the saturated soil-paste and estimates of saturation percentage. The amount of total dissolved solids in a sample is determined by weighing the residue obtained after evaporating a sample that has been filtered to remove particulate matter.
References
- Adams, F. 1974. Soil solution. .p. 441–481. In E. W. Carson (ed.) The plant root and its environment. Univ. Press Virginia, Charlottesville.
- Adams, F., C. Burmester, N.V. Hue, and F.L. Long 1980. A comparison of column-displacement and centrifuge methods for obtaining soil solutions. Soil Sci. Soc. Am. J. 44: 733–735.
- Allison, L.E. 1973. Oversaturation method for preparing saturation extracts for salinity appraisal. Soil Sci. 116: 65–69.
- American Society for Testing and Materials 1986. Annual book of ASTM standards. ASTM, Philadelphia, PA.Section 11. Vol. 11.01
- Beatty, H.J. and J. Loveday 1974. Soluble cations and anions. .p. 108–117. In J. Loveday (ed.) Methods for analysis of irrigated soils. Commonw. Bur. Soils, Commonw. Agric. Bur., Farmham Royal, Bucks, England.Tech. Commun. 54
- Bower, C.A. and L.V. Wilcox 1965. Solute salts. .p. 933–951. In C.A. Black et al. (ed.) Methods of soil analysis. ASA and SSSA, Madison, WI.SSSA Book Ser. 5
- Carlson, R.M., R. Overstreet, and D.J. Naylor 1971. Effect of microbial activity on saturation extract composition. Hilgardia. 40: 553–564.
-
Dao, T.H. and T.L. Lavy 1978. Extraction of soil solution using a simple centrifugation method for pesticide adsorption—desorption studies. Soil Sci. Soc. Am. J. 42: 375–377.
10.2136/sssaj1978.03615995004200020035x Google Scholar
- Davies, B.E. and R.I. Davies 1963. A simple centrifugation method for obtaining small samples of soil solution. Nature (London). 198: 216–217.
- Elkhatib, E.A., O.L. Bennett, V.C. Baligar, and R.J. Wright 1986. A centrifuge method for obtaining soil solution using an immiscible liquid. Soil Sci. Soc. Am. J. 50: 297–299.
- Elkhatib, E.A., J.L. Hern, and T.E. Staley 1987. A rapid centrifugation method for obtaining soil solu- tion. Soil Sci. Soc. Am. J. 51: 578–583.
- Gillman, G.P. 1976. A centrifuge method for obtaining soil solution. Div. Rep. 16. DivSoils, CSIRO, Townsville, Queensland, Australia.
- Grossman, J. and P. Udluft 1991. The extraction of soil water by the suction-cup method: A review. J. Soil Sci. 42: 83–93.
- K. Helrich 1990. Official methods of analysis. 15th Association of Official Analytical Chemists, Inc., Arlington, VA.
- Kinniburgh, D.G. and D.L. Miles 1983. Extraction and chemical analysis of interstitial water from soils and rocks. Environ. Sci. Technol. 17: 362–368.
- Kittrick, J.A. 1983. Accuracy of several immiscible displacement liquids. Soil Sci. Soc. Am. J. 47: 1045–1047.
- Litaor, M.I. 1988. Review of soil solution samplers. Water Resour. Res. 24: 727–733.
- Longenecker, D.E. and P.J. Lyerly 1964. Making soil pastes for salinity analysis: A reproducible cap- illary procedure. Soil Sci. 97: 268–275.
- Loveday, J. 1972. Moisture content of soils for making saturation extracts and effect of grinding. Commonw. Sci. Industr. Res. Organ., Canberra City.Div. Soils Tech. Pap. 12a ACT 2601, Australia
- Maas, E.V. 1986. Salt tolerance of plants. Appl. Agric. Res. 1: 12–26.
- Maas, E.V. 1990. Crop salt tolerance. .p. 262–304. In K.K. Tanji (ed.) Agricultural salinity assessment and management. ASCE, New York.ASCE Manuals Rep. Eng. 71
- Maas, E.V. and G.J. Hoffman 1977. Crop salt tolerance—current assessment. J. Irrig. Drainage Div., ASCE. 103 (IR2): 115–134.
- Menzies, N.W. and L.C. Bell 1988. Evaluation of the influence of sample preparation and extraction technique on soil solution composition. Aust. J. Soil Res. 26: 451–464.
- Mubarak, A. and R.A. Olsen 1976. Immiscible displacement of the soil solution by centrifugation. Soil Sci. Soc. Am. J. 40: 329–331.
-
Mubarak, A. and R.A. Olsen 1977. A laboratory technique for appraising in situ salinity of soil. Soil Sci. Soc. Am. J. 41: 1018–1020.
10.2136/sssaj1977.03615995004100050043x Google Scholar
- Prichard, T.L., G.J. Hoffman, and J.L. Meyer 1983. Salination of organic soils in the Sacramento-San Joaquin Delta of California. Irrig. Sci. 4: 71–80.
- Reitemeier, R.F. 1946. Effect of moisture content on the dissolved and exchangeable ions of soils of arid regions. Soil Sci. 61: 195–214.
- Rhoades, J.D. 1978. Monitoring soil salinity: A review of methods. .p. 150–165. In L.G. Everett, and K.D. Schmidt (ed.) Establishment of water quality monitoring programs. Am. Water Resour. Assoc, Minneapolis, MN.
- Rhoades, J.D. 1990. Determining soil salinity from measurements of electrical conductivity. Commun. Soil Sci. Plant Anal. 21: 861–901.
- Rhoades, J.D. 1992. Instrumental field methods of salinity appraisal. In G.C. Topp et al. (ed.) Advances in measurement of soil physical properties: Bringing theory into practice. ASA, CSSA, and SSSA, Madison, WI.SSSA Spec. Publ. 30
- Rhoades, J.D. and J.D. Oster 1986. Solute content. .p. 985–1006. In A. Klute (ed.) Methods of soil analysis. 2nd ASA and SSSA, Madison, WI.Agron. Monogr. 9
- Rhoades, J.D., N.A. Manteghi, P.J. Shouse, and W.J. Alves 1989a. Estimating soil salinity from saturated soil-paste electrical conductivity. Soil Sci. Soc. Am. J. 53: 428–433.
- Rhoades, J.D., B.L. Waggoner, P.J. Shouse, and W.J. Alves 1989b. Determining soil salinity from soil and soil-paste electrical conductivities: Sensitivity analysis of models. Soil Sci. Soc. Am. J. 53: 1368–1374.
- Rhoades, J.D., P.J. Shouse, W.J. Alves, N.A. Manteghi, and S.M. Lesch 1990. Determining soil salin- ity from soil electrical conductivity using different models and estimates. Soil Sci. Soc. Am. J. 54: 46–54.
- Richards, L.A. 1941. A pressure-membrane extraction apparatus for soil solution. Soil Sci. Soc. 51: 377–386.
- Richards, L.A. 1949. Filter funnels for soil extracts. Agron. J. 41: 446.
- Ross, D.S. and R.J. Bartlett 1990. Effects of extraction methods and sample storage on properties of solutions obtained from forested spodosols. J. Environ. Qual. 19: 108–113.
- Shimshi, D. 1966. Use of ceramic points for the sampling of soil solution. Soil Sci. 101: 98–103.
-
Skarie, R.L., J.L. Richardson, G.J. McCarthy, and A. Maianu 1987. Evaporite mineralogy and groundwater chemistry associated with saline soils in Eastern North Dakota. Soil Sci. Soc. Am. J. 51: 1372–1377.
10.2136/sssaj1987.03615995005100050050x Google Scholar
- Sonneveit, C. and J. van den Ende 1971. Soil analysis by means of a 1:2 volume extract. Plant Soil. 35: 505–516.
- Tadros, V.T. and J.W. McGarity 1976. A method for collecting soil percolate and soil solution in the field. Plant Soil. 44: 655–667.
- U.S. Salinity Laboratory Staff 1954. In L.A. Richards (ed.) Diagnosis and improvement of saline and alkali soils. USDA, Washington, DC.U.S. Dept. of Agriculture Handbook no. 60
- Wilcox, L.V. 1951. A method for calculating the saturation percentage from the weight of a known volume of saturated soil paste. Soil Sci. 72: 233–237.
- Wolt, J. and J.G. Graveel 1986. A rapid method for obtaining soil solution using vacuum displacement. Soil Sci. Soc. Am. J. 50: 602–605.
- Yamasuki, S. and A. Kishita 1972. Studies on soil solution with reference to nutrient availability. I. Effect of various potassium fertilizer on its behavior in the soil solution. Soil Sci. Plant Nutr. 18: 1–6.